Influence Assessment of Operating Parameters in Synthesis of Zn-Ni Alloys for Process Electrodeposition
Amarante, T.A.
Silva, S.C.
Almeida Neto, A.F.
Download PDF

How to Cite

Amarante T., Silva S., Almeida Neto A., 2017, Influence Assessment of Operating Parameters in Synthesis of Zn-Ni Alloys for Process Electrodeposition, Chemical Engineering Transactions, 57, 1651-1656.
Download PDF

Abstract

The influence of the variation of the metallic ions concentrations on the electrodeposition of Zn-Ni alloys on a copper substrate was studied evaluating the Faradaic efficiency. It was used a 22 factorial design, with 3 central points. So, fixing the electric current density in 12.5 mA/cm2, the variables were the concentrations of zinc and nickel. The electrolytic bath was composed by ZnSO4 and NiSO4, salts that were source of zinc and nickel, respectively, ammonium citrate as a complexing agent and sodium borate as an amorphising. The alloys showed good performance at room temperature and the Faradaic efficiency reached 95%. The concentration of zinc was more influential on the deposition efficiency than the concentration of nickel.
Download PDF