Abstract
Simultaneous separation of vapor and particles in industrial processes could be a key step toward manufacturing of high-quality goods. The separation is critical for successful measurement of volatile or semi-volatile aerosol particles, which no reliable technique exists. We have developed a technique for separation of vapor and particles simultaneously using a specialty microporous metallic membrane. The separator allows the thermally denuded particles traverse straight through the membrane tube, while the vapor molecules permeate through the membrane, separate from the particles and are removed subsequently. The separation technique virtually eliminates the possibility of contamination by vapor re-condensation. We tested the prototype of the vapor-particle separator (VPS) using aerosols prepared from sodium chloride to represent non-volatile aerosols. Chemical like dioctyl phthalate was chosen to represent volatile particles. The test aerosol particles were generated by an atomizer followed by a tandem differential mobility analyser to produce a stream of monodisperse particles in the size range of 10 to 100 nm. In real world particles, we tested the VPS using diesel engine particles that is a mixture of complex chemical composition. Number concentration of the nonvolatile particles reduced as the temperature increased, but the mode diameter of the aerosol population remained unchanged. Number concentration of the volatile particles was also reduced as the temperature increased, but their mode diameters became smaller as particles shrunk in diameter. Differences in the thermal behaviour of the particles were attributed to its transition energy barrier and evaporation rate. Mass balance analysis suggests the separation of vapor and test particles was reasonably complete. Thus, we conclude the VPS could provide an effective means for quantitative characterization of aerosol volatility and separation of vapors from particles.
