Comparative Studies of Low Temperature Water Gas Shift Reaction over Platinum Based Catalysts
Palma, V.
Pisano, D.
Martino, M.
Ricca, A.
Ciambelli, P.
Download PDF

How to Cite

Palma V., Pisano D., Martino M., Ricca A., Ciambelli P., 2014, Comparative Studies of Low Temperature Water Gas Shift Reaction over Platinum Based Catalysts, Chemical Engineering Transactions, 39, 31-36.
Download PDF

Abstract

Water gas shift reaction (WGS) is normally performed in a two-stage process, a first stage at high temperature (HTS) conventionally carried out at 623 - 873 K on Fe/Cr-based catalyst, to take advantage from a fast reaction, and a second stage at low temperature (LTS) at 423 - 573 K on Cu/Zn-based catalysts, to reach a favourable thermodynamic equilibrium condition. A single-stage process involves at the same time a cost reduction in plant setup as well as operative conditions; however at the moment, due to the lack of efficient catalytic systems the one-stage WGS systems is not widely diffused. Noble metals arise today as a promising solution in this direction, so in this work great attention was focused on the preparation and testing of differently-supported Platinum-based catalysts.
Download PDF