This study was started with the aim of evaluating different sampling techniques in order to develop a suitable and scientifically sound methodology for measuring the emissions of LFG from landfill surfaces. For this purpose, the work involved a bibliographical and theoretical study aiming to design new sampling equipment, as well as an experimental phase consisting in repeated measurement campaigns for the evaluation and comparison of such equipment on a sample site, i.e. a MSW landfill located in Northern Italy. Two sampling methods were designed and realized: a “flux chamber” and a “static box”. The results of the first sampling campaigns show a good agreement between the two sampling techniques, but further studies will be needed in order to validate those results and study the influence of the meteorological conditions on the measured LFG fluxes.