Application of Oxide Copper Chromium Catalysts for the Purification of Exhaust Gases
Baizhumanova, T.S.
Zheksenbaeva, Z.T.
Tungatarova, S.A.
Sarsenova, R.O.
Sadenova, M.A.
Abdulina, S.A.
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How to Cite

Baizhumanova T., Zheksenbaeva Z., Tungatarova S., Sarsenova R., Sadenova M., Abdulina S., 2016, Application of Oxide Copper Chromium Catalysts for the Purification of Exhaust Gases, Chemical Engineering Transactions, 52, 715-720.
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Abstract

Results of the development of multicomponent oxide catalysts based on Ni, Cu, and Cr supported on 2 % Ce/?-Al2O3 by varying the concentration of the active phase of catalyst are presented in paper. It was found that the highest degree of toluene conversion (up to 98.8 %) is observed on the three- component Ni-Cu-Cr/2% Ce/?-Al2O3 catalyst with optimal metal ratio Ni : Cu : Cr = 1.0 : 3.0 : 0.1 at GHSV = 5×103 h-1 and a temperature of 723 - 773 K. The presence of CeO2 crystals, X-ray amorphous clusters (d = 20 – 100 Å) of variable valence metal oxides NiO and CuO as well as solid metal solutions CuO (NiO) was detected on the surface of optimum catalyst calcined at 873 K using XRD and electron microscopy methods.
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