In order to verify the effect of logistics resource allocation efficiency on the production efficiency of chemical enterprises, the logistics resource allocation index system of chemical base is established by analyzing the logistics system and logistics resources of chemical base. Data envelopment analysis (DEA) is used to establish the evaluation model of resource allocation efficiency of logistics system in chemical base. Taking a large chemical industry base as the research object, the resource allocation efficiency of the chemical base is analyzed by using the evaluation system and model of the logistics resource allocation efficiency. The results show that the research on resource allocation efficiency of logistics system in chemical base can reduce resource redundancy. By adjusting the input structure of resources, the cost can be saved, and the benefit and industrial demonstration effect of chemical base can be improved.