The objective of this paper is to design and realize the logistic monitoring system for dangerous chemical products. As for problems of robbery accidents and leakage accidents during the transportation process of dangerous chemical products, the identification and tracking technology on moving objects in the real-time video stream transmission and video sequence are the main research objects; and the specific discussion and research on the video monitoring technology in the logistic monitor system of dangerous chemical products is carried out based on the research on theory principle and technology realization of existing video technology. The real-time transmission of video stream is achieved by collecting the video of YUV4:2:2 form, video coding & compression of H264 form and using RTP protocol, so that the identification and tracking on moving objects in the video sequence can be achieved. The experiment result indicates that the logistic monitoring system for dangerous chemical products designed in this paper can be effectively applied to identify the moving objects. Therefore, the logistic monitoring system for dangerous chemical products can be used to improve the stability and effectiveness of the transportation of dangerous chemical products.